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Self-test questions: Chapter 11
Return to Environmental Chemistry 4e student resources
Self-test questions: Chapter 11
Quiz Content
*
not completed
.
The value of Henry's Law constant for oxygen can be expressed as 1.3 x 10
-3
mol L
-1
atm
-1
. The SI unit for the constant is mol m
-3
Pa
-1
. What is the value using this SI unit?
1.3x10
-8
correct
incorrect
1.3x10
-5
correct
incorrect
0.77x10
-8
correct
incorrect
1.3x10
11
correct
incorrect
0.77x10
8
correct
incorrect
*
not completed
.
At 5
o
C, the equilibrium solubility of oxygen in water is 12.4 mg L
-1
. What is the value of the Henry's Law constant at this temperature? (Please select all that apply)
3.8x10
-9
mol L
-1
Pa
-1
correct
incorrect
3.9x10
-4
mol L
-1
atm
-1
correct
incorrect
3.8x10
-6
mol m
-3
Pa
-1
correct
incorrect
1.2x10
-7
mol L
-1
Pa
-1
correct
incorrect
7.6x10
-9
mol L
-1
Pa
-1
correct
incorrect
*
not completed
.
The Henry's Law constant for many gases when they dissolve in water is greater at low temperatures than at high temperatures. This implies that: Please select all that apply.
Dissolution is an exothermic process
correct
incorrect
Dissolution is an endothermic process
correct
incorrect
Entropy changes increase solubility at low temperatures
correct
incorrect
Water behaves anomalously compared to other liquids
correct
incorrect
The Henry's Law constants are not valid when water is the solvent
correct
incorrect
*
not completed
.
A small isolated lake with average depth of 12 m and having an alkalinity of 35 μmol L
-1
is subjected to 1200 mm of yearly rainfall with average pH 4.2. Assuming no removal of the added H
3
O
+
, how many years will it take to change the lake status from 'transitional' to 'acidic'?
0.46
correct
incorrect
0.18
correct
incorrect
2.9
correct
incorrect
5.5
correct
incorrect
34
correct
incorrect
*
not completed
.
In recent history the average ocean pH has been 8.2, but within another 30 years, the average is expected to be 8.0. What would be the percentage increase in hydrogen ion?
2.0
correct
incorrect
58
correct
incorrect
-19
correct
incorrect
-2.0
correct
incorrect
72
correct
incorrect
*
not completed
.
The following equation describes the basic chemical equilibria of CO
2
in the ocean (at pH 8.2)
CO
2
(g) ←→ CO
2
(aq) + H
2
O ←→ H
2
CO
3
←→ H
+
+ HCO
3
−
←→ 2H
+
+ CO
3
2-
(Please select all that apply)
In the oceans, most of the dissolved carbon dioxide is in the HCO
3
-
form
correct
incorrect
Acidification causes an increase in CO
3
2-
concentrations in the ocean
correct
incorrect
Photosynthetic rates are also suppressed by increased CO
2
in the seawater
correct
incorrect
H
+
will increase with increasing CO
3
2-
correct
incorrect
H
+
will increase with increasing HCO
3
-
correct
incorrect
*
not completed
.
Which of the following statements about ocean acidification is/are true? (Please select all that apply)
A decrease in pH of seawater from 8.2 to 8.1 means an approximate 10% increase in acidity
correct
incorrect
For carbon dioxide, the K
a
values are smaller in seawater than in fresh water
correct
incorrect
For a calcium carbonate, a value of Q
sp
/K
sp
that is greater than 1 means that there is a tendency for dissolution to occur
correct
incorrect
Carbon dioxide is the only acid causing an increase in ocean acidity
correct
incorrect
CO
3
2-
is the principal species of the carbonate system in seawater
correct
incorrect
*
not completed
.
Which of the following statements about alkalinity is/are true? (Please select all that apply)
A lake with a pH of 9.5 always has a high alkalinity
correct
incorrect
Natural organic matter (NOM) is included in the measurement of alkalinity
correct
incorrect
The molar concentration of carbonate is multiplied by 2 in the determination of alkalinity
correct
incorrect
Acid neutralizing capacity (ANC) is the same as alkalinity, just using a more scientific name
correct
incorrect
Alkalinity is a capacity factor, allowing you to know the ability of a water sample to sustain reactions with added acids or bases
correct
incorrect
*
not completed
.
Which of the following statements about lake acid/base properties is/are true? (Please select all that apply)
A well-buffered lake has a high acid neutralizing capacity and a pH around 6.5
correct
incorrect
A lake that has just fallen into the transitional range will turn acidic within a few months
correct
incorrect
A lake with a pH of 6.5 will still have some alkalinity in it
correct
incorrect
A lake with an alkalinity of 22 mg CaCO
3
2-
L
-1
is considered to be a lake that is sensitive to acid input
correct
incorrect
The pH of a lake does not matter as long as the alkalinity is high enough
correct
incorrect
*
not completed
.
Which of the following statements about alkalinity is/are true? (Please select all that apply)
Alkalinity can be expressed using units of mg L
-1
CaCO
3
correct
incorrect
Alkalinity is a measure of the ability of a water body to neutralize acidity
correct
incorrect
Alkalinity of 100 mg L
-1
for a lake is considered to be a high value
correct
incorrect
Alkalinity can be expressed using units of μmol L
-1
of proton acceptors
correct
incorrect
Alkalinity is analogous to the inverse of pH
correct
incorrect
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