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Chapter 7 Multiple Choice Questions
Return to Inorganic Chemistry 7e student resources
Chapter 7 Multiple Choice Questions
An introduction to coordination compounds
Quiz Content
*
not completed
.
Identify the correct statement:
The inner-sphere complex together with the outer-sphere complex form a coordination compound.
correct
incorrect
In the inner-sphere complex the ligands are attached directly to the central metal atom or ion while the outer-sphere complex is formed through electrostatic association between complex cations and anions.
correct
incorrect
The outer-sphere complex is always present and follows its inner-sphere counterpart.
correct
incorrect
*
not completed
.
The ligand is:
a donor that provides an electron pair to form the bond in the complex; it is a Lewis base
correct
incorrect
an acceptor atom that accepts electron pair to form the bond in the complex; it is a Lewis acid
correct
incorrect
a donor that provides electrons to form the bond in the complex; it is a Lewis acid
correct
incorrect
*
not completed
.
The coordination number of the central metal atom in the complexes [AgCl
2
]
–
, Me–Hg–Me, and Cu(acac)
2
(acac is an acronym for acetylacetonato ligand) is:
one in [AgCl
2
]
–
and two in Me-Hg-Me and Cu(acac)
2
correct
incorrect
two in all of them
correct
incorrect
two [AgCl
2
]
–
and Me-Hg-Me, but four in Cu(acac)
2
correct
incorrect
*
not completed
.
If the central atom has a coordination number of four, then the geometry of the complexes is:
tetrahedral, if the central atom is small and the ligands are large
correct
incorrect
square planar, if the central atom is small and the ligands are large
correct
incorrect
tetrahedral, if the central atom is small and has a d
8
electronic configuration
correct
incorrect
*
not completed
.
The aqua complex of Nd
3+
is most likely to exhibit a coordination number of:
15
correct
incorrect
6
correct
incorrect
9
correct
incorrect
*
not completed
.
Chelates are complexes that can be formed by:
monodentate ligands
correct
incorrect
ambidentate ligands
correct
incorrect
polydentate ligands
correct
incorrect
*
not completed
.
The compounds [Cr(H
2
O)
6
]Cl
3
, [Cr(H
2
O)
5
Cl]Cl
2
·H
2
O, and [Cr(H
2
O)
4
Cl
2
]Cl·2H
2
O are examples of:
hydrate isomerism
correct
incorrect
ionization isomerism
correct
incorrect
coordination isomerism
correct
incorrect
*
not completed
.
Which statement is correct?
Tetrahedral complexes can form optical isomers.
correct
incorrect
Complexes with the general formula MA
4
B
2
can form
mer
- and
fac
-isomers.
correct
incorrect
Complexes with the general formula MA
3
B
3
can form
cis
- and
trans
-isomers.
correct
incorrect
*
not completed
.
Which of the following octahedral complexes could exhibit chirality:
[MA
2
B
2
C
2
]
correct
incorrect
[MA
3
B
2
C]
correct
incorrect
[MA
4
B
2
]
correct
incorrect
*
not completed
.
The formation constant,
K
f
, of a complex is a measure of:
the rate at which a complex is formed from the metal ions and the ligands in the gas phase
correct
incorrect
the strength of the interaction between the ligands and the metal center relative to the strength of interaction between the solvent molecules and the metal center
correct
incorrect
the rate at which the complex enters in chemical reactions
correct
incorrect
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