Calculate the change in the molar entropy of a perfect gas when it is compressed isothermally from a pressure of 1 bar to 10 bar.
Calculate the change in the standard molar entropy of hydrogen chloride, HCl, gas when it is heated from a temperature of 20°C to 30°C. The standard molar constant-pressure heat capacity of hydrogen chloride is 29.1 J K–1 mol–1.
The standard enthalpy of sublimation of carbon dioxide is 26.2 kJ K–1 mol–1 at 298.15 K. Calculate the standard entropy of sublimation at this temperature.
The boiling temperature of ethylbenzene is 136 °C. Use Trouton's rule to estimate the enthalpy of vaporization of ethylbenzene at this temperature.
Calculate the change in entropy when exactly 1 mol of solid iodine, I2, at a temperature of 360 K is heated at constant pressure to produce liquid iodine at a temperature of 410 K. The constant pressure molar heat capacity of solid iodine is 54.44 J K–1 mol–1 and of liquid iodine is 80.67 J K–1 mol–1. The melting temperature of iodine is 387 K, and the molar enthalpy of fusion of iodine is 7.87 kJ mol–1.
At low temperatures, the heat capacity of solid chlorine, Cl2, follows the Debye T3 law, Cp,m = a T3, with a = 1.24 ´ 10–3 J K–4 mol–1. Estimate the molar entropy of solid chlorine at 10 K.
Which of the following conditions is necessary for a reaction to be spontaneous?
A hypothetical system consists of 5 molecules and 2 quanta. What is the number of possible arrangements?
For a spontaneous change in a system at constant temperature and pressure, which of the following statements is true?
Which of the following statements is always true for a system at equilibrium under conditions of constant temperature and pressure?
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