Self-test questions: Chapter 17

Self-test questions: Chapter 17

Quiz Content

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Determine the vapour pressure of n-butanol, C4H10O, at a temperature of 298 K, given that the normal boiling temperature is 391 K and enthalpy of vaporization is 52.1 kJ mol–1.

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The normal boiling temperature of 1,1,1-trichloroethane, C2H3Cl3, is 74°C, and the specific enthalpy of vaporization is 32.5 kJ mol–1.Determine the vapour pressure at a temperature of 298 K.

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The Henry's law constant for nitrogen dissolved in water at 298 K is 8.68 ´ 109 Pa. Determine the fractional amount of nitrogen in water in equilibrium with air at a pressure of 1.2 atm and temperature of 298 K.

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What is the osmotic pressure generated at 25°C by a solution of 2.10 g of sucrose, C12H22O11, in 100 cm3 of water?

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Determine the mass of sucrose, C12H22O11, that must be added to water to create an aqueous solution of volume 0.05 dm3 with an osmotic pressure of 1.0 atm.

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Estimate the increase in the vapour pressure of 1-heptanol, C7H16O, from when the temperature is 350 K to when the temperature is 400 K. The normal boiling temperature is 448 K and enthalpy of vaporization is 67.1 kJ mol–1.

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Estimate the change in the vapour pressure of ethanoic acid, C2H4O, from when the temperature is 300 K to when the temperature is 320 K. The normal boiling temperature is 391 K and enthalpy of vaporization is 50.3 kJ mol–1.

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What is the osmotic pressure generated at 25°C by a solution of 1.00 g of glucose, C6H12O6, in 1000 cm3 of water at 298 K?

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Determine the mass of sucrose, C12H22O11, that must be added to water to create an aqueous solution of volume 0.10 dm3 with an osmotic pressure of 1.0 atm at 298 K.

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0.25 g of a protein is added to 500 cm3 water at 25 °C and the osmotic pressure is measured as 350 Pa. Estimate the relative molecular mass of the protein.

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