Self-test questions: Chapter 13

Self-test questions: Chapter 13

Quiz Content

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The molar heat capacity, Cm of gold (Fe(s)) is 25.1 J K-1 mol-1. Calculate the energy (in J) required to heat a 25 g bar of iron from 50 °C to 75 °C.

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The specific heat capacity of liquid water is 4.18 J K-1 g-1. Calculate the temperature rise (in K) when 350 J of heat is transferred to 3 mol of water.

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The specific heat capacity of iron (Fe(s)) is 0.38 J K-1 g-1, how much energy (in J) must be added to raise the temperature of a 100 g copper bar by 25 °C?

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The standard enthalpy change of vaporization of ethanol is + 43.5 kJ mol-1. Calculate the enthalpy change (in kJ) when 23 g of ethanol vaporizes at its boiling point at 1 bar.

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Calculate the standard enthalpy change (in kJ mol-1) for the hydrogenation of pentene to pentane at 298 K. The standard enthalpy change at 298 K for reactions of graphite and hydrogen gas to form 1 mol of each of these compounds is −21.7 kJ mol-1 and −146.8 kJ mol-1 respectively.

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Calculate for the oxidation of 2-propanol to propanone:

C3H7OH (g)+ ½ O2 (g)→ C3H6O (g) + H2O (g)

using the bond enthalpies given in Table 13.5

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The enthalpy change for a reaction at 298 K is –35.5 kJ mol-1.

Calculate the enthalpy change at 333 K if the difference in heat capacities between reactants and products, DCPis 14.4 J mol−1 K−1.

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A reaction produces carbon dioxide gas. A balloon attached to the reaction vessel expands against a constant pressure of 1.1 atm and at the end of the reaction it is calculated that 2.5 dm3 of CO2 (g) has been produced. Calculate the energy transferred as work, w, (in J).

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One mole of gas is heated with 4.2 kJ of energy; it expands doing 3250 J of work. Calculate the change in internal energy of the gas.

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The combustion of benzoic acid at 1 bar and 298 K releases 3228 kJ mol-1 of heat.

C7H6O (s) + 8 O2 (g) → 7 CO2 (g) + 3 H2O (l) Calculate (in kJ mol-1) for benzoic acid.

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