Self-test questions: Chapter 10

Self-test questions: Chapter 10

Quiz Content

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The transmittance of an aqueous solution that contained Cu2+ ions at a concentration of 0.05 mol L-1 at 600nm was measured at 0.30 in a cell of length 1.0 cm. The molar absorption coefficient is:

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An absorption occurs in the infrared spectrum at 1700 cm−1. The energy of this transition is:

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The spacing between the rotational lines in the microwave spectrum of the 35Cl16O radical is 1.2490 cm−1. If the reduced mass of ClO is 1.824 × 10−26 kg, the Cl−O bond length is:

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Which of the following will not show infrared spectra

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1H19F absorbs infrared radiation of wavenumber 4138cm−1. Calculate the force constant of the HF bond, if the reduced mass is 1.58 × 10−27 kg.

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How many vibrational modes exist for the molecule N2O?

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Hydrogen bromide (1H81Br) has a vibrational wavenumber of 2649 cm−1. The energy difference between v = 0 and v = 1 levels is:

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In order of increasing energy, the lines observed in Raman spectroscopy are:

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In a 1H NMR spectrum recorded on a 600 MHz spectrometer, a signal is observed at 2.5 ppm relative to the standard (at 0 ppm). Calculate the frequency of absorption giving rise to this signal.

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Which of the following is true for rotational spectroscopy?

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