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Self-test questions: Chapter 20
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Self-test questions: Chapter 20
Quiz Content
*
not completed
.
Which one(s) of these statements is/are true? (Please select all that apply)
Log K
ow
for fat-soluble organic species tend to be large values
correct
incorrect
A correlation is expected between log K
ow
and log BCF
correct
incorrect
A large LD
50
value signifies high toxicity
correct
incorrect
R
f
values are inversely related to log K
om
correct
incorrect
A low R
f
value indicates a high mobility in a soil for a pesticide
correct
incorrect
*
not completed
.
Which one(s) of these statements is/are true? (Please select all that apply)
Degradation t
1/2
values for organophosphorus pesticides are generally greater than those for organochlorine pesticides
correct
incorrect
For a pesticide, a high R
f
value signifies high mobility in soil
correct
incorrect
For a pesticide, a high log K
om
signifies high mobility in soil
correct
incorrect
Leachability of a pesticide depends on both its half-life and its K
om
correct
incorrect
Vaporization is not considered as an aspect of pesticide mobility in a soil
correct
incorrect
*
not completed
.
Which one(s) of these statements is/are true? (Please select all that apply)
K
om
f
om
= K
oc
f
oc
correct
incorrect
K
d
= K
om
x f
om
correct
incorrect
K
oc
= K
om
x 1.7
correct
incorrect
K
d
= f
om
x C
om
/ C
aq
correct
incorrect
K
d
= 1/R
f
correct
incorrect
*
not completed
.
Which of the following properties of biocides is/are true? (Please select all that apply)
Chlorine in an organic compound usually enhances its chemical stability
correct
incorrect
Dermal LD
50
and LC
50
values are usually higher than are oral values
correct
incorrect
The leachability of compounds is connected with their chemical stability
correct
incorrect
Oxygen-containing organophosphorus pesticides are more toxic than their sulfur-containing analogues
correct
incorrect
The reaction products of some pesticides are more toxic than the parent compound
correct
incorrect
*
not completed
.
Which of the following statements about degradation of biocides is/are true? (Please select all that apply)
Molecules that absorb radiation of wavelengths <250 nm and have small bond enthalpy values are subject to photolytic degradation by sunlight
correct
incorrect
Direct photolytic reactions follow first-order or pseudo-first-order kinetics
correct
incorrect
The rate of indirect photolysis is given by rate = f[sensitizer][receptor]
correct
incorrect
Hydrolysis at the phosphorus centre of organophosphorus compounds is a common reaction
correct
incorrect
Hydrolysis of biocides is a purely abiotic process
correct
incorrect
*
not completed
.
Which of the following statements about degradation of biocides is/are true? (Please select all that apply)
Biologically mediated oxidation is a common process by which hydrocarbons are degraded
correct
incorrect
A high p
E
environment favours dehalogenation or halogenated organic compounds
correct
incorrect
Low molar mass hydrocarbons decompose more rapidly than high molar mass ones
correct
incorrect
At field capacity, many degradation reactions in soil occur at their optimum rate
correct
incorrect
High organic matter content in a soil often inhibits degradation of organic biocides
correct
incorrect
*
not completed
.
Which of the following statements about environmental behaviour of biocides is/are true? (Please select all that apply)
The grasshopper effect describes how semi-volatile biocides move from place to place depending on wind currents
correct
incorrect
The GUS index combines information about toxicity and degradative half-life of a biocide
correct
incorrect
A plot of equilibrium vapour pressure of a biocide vs water content of a soil often increases to a plateau as soil moisture content increases
correct
incorrect
It is commonly found that log K
OA
values increase linearly with temperature
correct
incorrect
K
om
and R
f
values are inversely related
correct
incorrect
*
not completed
.
Which of the following statements about environmental behaviour of biocides is/are true? (Please select all that apply)
The oral LD
50
for a pesticide in water uses units of mg (pesticide) L
-1
(water)
correct
incorrect
Organochlorine compounds often have a very large LD
50
value, indicating high toxicity
correct
incorrect
Intraparticle diffusion can frequently inhibit leaching of a biocide
correct
incorrect
Biocides with cationic components usually have limited mobility in soils
correct
incorrect
Organic matter in soil is one factor that encourages retention of biocides
correct
incorrect
*
not completed
.
Which of the following chemicals belong to the category euphemistically known as 'the dirty dozen' persistent organic pollutants (POPs)? (Please select all that apply)
Dioxins and furans
correct
incorrect
PAHs
correct
incorrect
Perfluorooctane sulfonic acid (PFOS)
correct
incorrect
Toxaphene, aldrin, endrin
correct
incorrect
DDT, PCBs, hexachlorobenzene
correct
incorrect
*
not completed
.
Based on the data in Table 20.6, which of the following is a currently used controversial pesticide having a pseudo first-order decay constant of approximately 1.1x10
-7
s
-1
?
Metolachlor
correct
incorrect
Carbaryl
correct
incorrect
Heptachlor
correct
incorrect
Atrazine
correct
incorrect
Chlorpyrifos
correct
incorrect
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