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Self-test questions: Chapter 04
Return to Environmental Chemistry 4e student resources
Self-test questions: Chapter 04
Quiz Content
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not completed
.
Which of the following conditions is/are needed for photochemical smog formation? (Please select all that apply)
A stable atmosphere
correct
incorrect
Warm or hot temperatures
correct
incorrect
Emissions of nitrous oxide
correct
incorrect
Intense sunlight
correct
incorrect
Emissions of volatile organic compounds
correct
incorrect
*
not completed
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Which of the following reactions is/are part of the smog generation sequence? (Please select all that apply)
O
2
+ hν → O + O
correct
incorrect
NO
2
+ hν → NO + O
correct
incorrect
O* + H
2
O → 2 •OH
correct
incorrect
NO
2
+ H
2
O → NO + 2 •OH
correct
incorrect
O
3
+ hν → O
2
* + O*
correct
incorrect
*
not completed
.
Ethanol, produced as a biofuel, has the following advantage(s) over petroleum fuels: (Please select all that apply)
It is an oxygenating fuel, promoting more complete combustion
correct
incorrect
It produces more energy per volume than petroleum-based fuels
correct
incorrect
During combustion it releases less CO than petroleum-based fuels
correct
incorrect
It is produced from a renewable resource
correct
incorrect
Reduced volatility means reduced release of VOCs from the gas tank
correct
incorrect
*
not completed
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Which of these compounds is/are part of the smog-generating sequence? (Please select all that apply)
NO
2
correct
incorrect
NO
correct
incorrect
N
2
O
correct
incorrect
CO
correct
incorrect
O
3
correct
incorrect
*
not completed
.
Which of the following statements about smog formation is/are true? (Please select all that apply)
Both thermal and photochemical reactions are involved in creating a photochemical smog
correct
incorrect
Sulfur compounds from coal burning are a major contributor to photochemical smog
correct
incorrect
Natural gas, as a fuel, does not contribute to emission of smog-producing chemicals
correct
incorrect
An atmospheric inversion means that cooler air is present near the Earth's surface
correct
incorrect
Components of both classical and photochemical smog can be present together
correct
incorrect
*
not completed
.
Which of the following statements about smog formation is/are true? (Please select all that apply)
Carbon monoxide oxidation is a part of the photochemical smog formation reaction sequence
correct
incorrect
Fuels high in nitrogen content are the source of nitrous oxide emitted from automobiles
correct
incorrect
Photolysis of nitrogen dioxide produces atomic oxygen that is a precursor of ozone
correct
incorrect
Hydroxyl radical concentrations are generally higher in tropical atmospheres than in temperate ones
correct
incorrect
Peroxy radicals are part of the reaction sequence that leads to oxidation of hydrocarbons
correct
incorrect
*
not completed
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Which of the following statements about smog formation is/are true? (Please select all that apply)
Reactions of hydroxyl radical with olefins usually begin with abstraction of a hydrogen atom
correct
incorrect
Phenols are one product of the oxidation of aromatic compounds in the atmosphere
correct
incorrect
Peroxy species react with nitrous oxide to form nitrate ion
correct
incorrect
PANs act as relatively stable reservoirs of nitrogen oxides
correct
incorrect
For hydrocarbons, hydroxyl radicals are the most important initiator of the smog reaction sequence
correct
incorrect
*
not completed
.
Which of the following statements about VOC oxidation is/are true? (Please select all that apply)
For alkynes, the initial reaction step in their oxidation is to add a hydroxyl at the triple bond
correct
incorrect
Aldehydes are involved in the formation of PANs
correct
incorrect
Hydrogen abstraction or hydroxyl addition to a VOC both lead to formation of radicals
correct
incorrect
Photolysis of aldehydes in the atmosphere leads to immediate production of carbon dioxide
correct
incorrect
In an urban atmosphere, hydrocarbon concentrations tend to decrease during the day
correct
incorrect
*
not completed
.
Which of the following statements about internal combustion engines is/are true? (Please select all that apply)
Using fuels with a high octane number increases the compression ratio of the engine
correct
incorrect
Large air to fuel ratios in an engine increases production of nitric oxide
correct
incorrect
The fuel additive, tetraethyl lead, by acting as an oxygenating agent, is used to augment the octane number of gasoline
correct
incorrect
The compression ratio equals the work done by an engine over the heat input
correct
incorrect
Both rich and lean fuel/air ratios can lead to production of photochemical smog precursors
correct
incorrect
*
not completed
.
Which of the following statements about internal combustion engines is/are true? (Please select all that apply)
In two-stroke engines, mixing of exhaust gases and fresh fuel/air mixtures occurs
correct
incorrect
Nitric oxide production is intrinsically greater in a diesel compared to a gasoline engine
correct
incorrect
Catalytic converters are available that can simultaneously reduce emissions of nitric oxide and VOCs from a gasoline engine
correct
incorrect
Biodiesel fuels generate lower concentrations of partially-burned carbon-containing products than petroleum diesel
correct
incorrect
It is not possible to use emission catalysts to reduce harmful exhaust gases from a two-stroke engine
correct
incorrect
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